EJERCICIO 8.

26

SOLUCION
Datos de Cp Praunitz

tabla de datos CpA

CpB
CpC
CpD
CpH
etilbenceno
-43.1
0.7072 -0.0004811
1.301E-07
29810
estireno
-28.25
0.6159 -0.0004023
9.935E-08
147500
H2
27.14
0.009274 0.00001381
7.645E-09
0
benceno
-33.92
0.4739 -0.0003017
7.13E-08
82980
etileno
3.806
0.1566 0.00008348
1.755E-08
52340
Tolueno
-24.35
0.5125 -0.0002765
4.911E-08
50030
metano
19.25
0.05213 0.00001197 -1.132E-08
-74900
vapor de agua
32.24
0.001924 0.00001055 -3.596E-09
-242000
tabla de cpi
Rxn1
Rxn2
Rxn3

CpA

CpB
CpC
CpD
CpH
41.99 -0.082026
6.499E-05 -2.3105E-08
117690
12.986
-0.0767 0.00009592 -4.125E-08
105510
10.86 -0.151844 0.00023038 -9.9955E-08
-54680

PARTE A
d(FeB)/d(v) = -r1 - r2 - r3
FeB(0) = 0.00344
d(FB)/d(v) = r2
FB(0) = 0
d(FH)/d(v) = r1 - r3
FH(0) = 0
d(Fst)/d(v) = r1
Fst(0) = 0
d(FT)/d(v) = r3
FT(0) = 0
d(Fm)/d(v) = r3
Fm(0) = 0
d(Fet)/d(v) = r2
Fet(0) = 0
r1 = p * (1 - phi) * exp(-0.08539 - 10925 / T) * (PeB - Pst * PH / Kp1)
r2 = p * (1 - phi) * exp(13.2392 - 25000 / T) * (PeB)
r3 = p * (1 - phi) * exp(.2961 - 11000 / T) * (PeB * PH)
p = 2137
phi = 0.4
PeB = (Fto * R * T / vo) * FeB / Ft
PH = (Fto * R * T / vo) * FH / Ft
Pst = (Fto * R * T / vo) * FeB / Ft
Ft = FeB + FH + FB + Fst + FT + Fm + Fet + Fi
Fto = 0.00344 + Fi
Fi = 14.5 * 0.00344

CpeB = -43.1 + 0.7072 * T - 0.0004811 * T ^ 2 + 1.301 * 10 ^ -7 * T ^ 3

CpH = 27.14 + 0.009274 * T - 0.00001381 * T ^ 2 + 7.645 * 10 ^ -9 * T ^ 3
CpB = -33.92 + 0.4739 * T - 0.0003017 * T ^ 2 + 7.13 * 10 ^ -8 * T ^ 3
Cpst = -28.25 + 0.6159 * T - 0.0004023 * T ^ 2 + 9.935 * T ^ 3 * 10 ^ -8
CpT = -24.35 + 0.5125 * T - 0.0002765 * T ^ 2 + 4.911 * 10 ^ -8 * T ^ 3
Cpm = 19.25 + 0.05213 * T + 0.00001197 * T ^ 2 - 1.132 * 10 ^ -8 * T ^ 3
Cpet = 3.806 + 0.1566 * T - 0.00008348 * T ^ 2 + 1.755 * 10 ^ -8 * T ^ 3
Cpi = 32.24 + 0.001924 * T + 0.00001055 * T ^ 2 - 3.596 * 10 ^ -9 * T ^ 3
Kp1 = exp(-17.34 + -1.302 * 10 ^ 4 / T + 5.051 * ln(T) + ((-2.314 * 10 ^ -10 * T + 1.302 * 10 ^ -6) * T
+ -4.931 * 10 ^ -3) * T)
DH1eB = 117690 + int1
int1 = 41.99 * T - .082026 * T ^ 2 / 2 + 6.499 * 10 ^ -5 / 3 * T ^ 3 - 2.3105 * 10 ^ -8 / 4 * T ^ 4
DH2eB = 105510 + int2
int2 = 12.986 * T - .0767 / 2 * T ^ 2 + 0.00009592 / 3 * T ^ 3 - 4.125 * 10 ^ -8 / 4 * T ^ 4
DH3eB = -54680 + int3
int3 = 10.86 * T - .151844 / 2 * T ^ 2 + .00023038 / 3 * T ^ 3 - 9.9955 * 10 ^ -8 / 4 * T ^ 4
d(T)/d(v) = (-DH1eB * r1 - DH2eB * r2 - DH3eB * r3) / (FeB * CpeB + FH * CpH + FB * CpB + Fst *
Cpst + FT * CpT + Fm * Cpm + Fet * Cpet + Fi * Cpi)
T(0) = 800
R = 0.0821357
vo = (Ft * R * T) / P
v(0) = 0
v(f) = 10
P = 2.4

Calculated values of DEQ variables

Variable Initial value Minimal value Maximal value Final value
1

10.

10.

FeB

0.00344

0.0028465

0.00344

0.0028465

FB

1.277E-05

1.277E-05

FH

0.0005222

0.0005222

Fst

0.0005515

0.0005515

FT

2.925E-05

2.925E-05

Fm

2.925E-05

2.925E-05

Fet

1.277E-05

1.277E-05

800.

774.6374

800.

774.6374

10 P

2.4

2.4

2.4

2.4

11 Fi

0.04988

0.04988

0.04988

0.04988

12 Ft

0.05332

0.05332

0.0538842

0.0538842

13 p

2137.

2137.

2137.

2137.

14 phi

0.4

0.4

0.4

0.4

15 Fto

0.05332

0.05332

0.05332

0.05332

16 R

0.0821357

0.0821357

0.0821357

0.0821357

17 vo

1.459825

1.428502

1.459825

1.428502

18 Pst

0.1548387

0.125456

0.1548387

0.125456

19 PeB

0.1548387

0.125456

0.1548387

0.125456

20 PH

0.0230163

0.0230163

21 CpeB

281.3672

276.5078

281.3672

276.5078

22 CpH

29.63504

29.59075

29.63504

29.59075

23 CpB

188.6176

185.2841

188.6176

185.2841

24 Cpst

257.8652

253.6248

257.8652

253.6248

25 CpT

233.8343

229.5621

233.8343

229.5621

26 Cpm

62.81896

61.55271

62.81896

61.55271

27 Cpet

84.6444

83.17874

84.6444

83.17874

28 Cpi

38.69005

38.38954

38.69005

38.38954

29 Kp1

0.0459123

0.0249064

0.0459123

0.0249064

30 int1

1.607E+04

1.591E+04

1.607E+04

1.591E+04

31 DH1eB

1.338E+05

1.336E+05

1.338E+05

1.336E+05

32 int2

-2008.853

-2008.853

-1804.053

-1804.053

33 DH2eB

1.035E+05

1.035E+05

1.037E+05

1.037E+05

34 int3

-1.082E+04

-1.082E+04

-1.045E+04

-1.045E+04

35 DH3eB

-6.55E+04

-6.55E+04

-6.513E+04

-6.513E+04

36 r2

2.991E-06

8.712E-07

2.991E-06

8.712E-07

37 r3

3.392E-06

3.389E-06

38 r1

0.0002138

8.404E-06

0.0002138

8.404E-06

PARTE B (cambiamos To=930K)

Calculated values of DEQ variables
Variable Initial value Minimal value Maximal value Final value
1

10.

10.

FeB

0.00344

0.0010657

0.00344

0.0010657

FB

0.0001982

0.0001982

FH

0.0018187

0.0018187

Fst

0.0019974

0.0019974

FT

0.0001787

0.0001787

Fm

0.0001787

0.0001787

Fet

0.0001982

0.0001982

930.

837.8572

930.

837.8572

10 P

2.4

2.4

2.4

2.4

11 Fi

0.04988

0.04988

0.04988

0.04988

12 Ft

0.05332

0.05332

0.0555156

0.0555156

13 p

2137.

2137.

2137.

2137.

14 phi

0.4

0.4

0.4

0.4

15 Fto

0.05332

0.05332

0.05332

0.05332

16 R

0.0821357

0.0821357

0.0821357

0.0821357

17 vo

1.697047

1.591862

1.697047

1.591862

18 Pst

0.1548387

0.0442499

0.1548387

0.0442499

19 PeB

0.1548387

0.0442499

0.1548387

0.0442499

20 PH

0.0755138

0.0755138

21 Kp1

0.6304376

0.1069174

0.6304376

0.1069174

22 CpeB

303.1395

288.2203

303.1395

288.2203

23 CpH

29.96986

29.71224

29.96986

29.71224

24 CpB

203.2173

193.2829

203.2173

193.2829

25 Cpst

276.5006

263.8054

276.5006

263.8054

26 CpT

252.6321

239.833

252.6321

239.833

27 Cpm

68.97843

64.6723

68.97843

64.6723

28 Cpet

91.35861

86.73364

91.35861

86.73364

29 Cpi

40.26155

39.14309

40.26155

39.14309

30 int1

1.668E+04

1.629E+04

1.668E+04

1.629E+04

31 DH1eB

1.344E+05

1.34E+05

1.344E+05

1.34E+05

32 int2

-3088.247

-3088.247

-2317.51

-2317.51

33 DH2eB

1.024E+05

1.024E+05

1.032E+05

1.032E+05

34 int3

-1.249E+04

-1.249E+04

-1.134E+04

-1.134E+04

35 DH3eB

-6.717E+04

-6.717E+04

-6.602E+04

-6.602E+04

36 r2

0.000236

3.508E-06

0.000236

3.508E-06

37 r3

2.813E-05

1.145E-05

38 r1

0.001442

3.325E-05

0.001442

3.325E-05

39 SstBT

6.109339

2.223377

6.878866

2.223377

PARTE C (T(0) = 1010)

Calculated values of DEQ variables
Variable Initial value Minimal value Maximal value Final value
1

10.

10.

FeB

0.00344

0.0001646

0.00344

0.0001646

FB

0.0006205

0.0006205

FH

0.0022731

0.0022731

Fst

0.002464

0.002464

FT

0.0001909

0.0001909

Fm

0.0001909

0.0001909

Fet

0.0006205

0.0006205

1010.

885.6751

1010.

885.6751

2.4

2.4

2.4

2.4

10 P

11 Fi

0.04988

0.04988

0.04988

0.04988

12 Ft

0.05332

0.05332

0.0564045

0.0564045

13 p

2137.

2137.

2137.

2137.

14 phi

0.4

0.4

0.4

0.4

15 Fto

0.05332

0.05332

0.05332

0.05332

16 R

0.082057

0.082057

0.082057

0.082057

17 vo

1.841263

1.708018

1.841263

1.708018

18 Pst

0.1548387

0.0066224

0.1548387

0.0066224

19 PeB

0.1548387

0.0066224

0.1548387

0.0066224

20 PH

0.0914323

0.0914323

21 Kp1

2.269797

0.2809698

2.269797

0.2809698

22 CpeB

314.4441

296.2507

314.4441

296.2507

23 CpH

30.29581

29.8322

30.29581

29.8322

24 CpB

210.4153

198.6769

210.4153

198.6769

25 Cpst

285.7832

270.6875

285.7832

270.6875

26 CpT

261.8154

246.785

261.8154

246.785

27 Cpm

72.44889

66.94528

72.44889

66.94528

28 Cpet

94.89583

89.21202

94.89583

89.21202

29 Cpi

41.24033

39.72138

41.24033

39.72138

30 int1

1.688E+04

1.651E+04

1.688E+04

1.651E+04

31 DH1eB

1.346E+05

1.342E+05

1.346E+05

1.342E+05

32 int2

-3794.047

-3794.047

-2713.379

-2713.379

33 DH2eB

1.017E+05

1.017E+05

1.028E+05

1.028E+05

34 int3

-1.336E+04

-1.336E+04

-1.196E+04

-1.196E+04

35 DH3eB

-6.804E+04

-6.804E+04

-6.664E+04

-6.664E+04

36 r2

0.0019846

2.629E-06

0.0019846

2.629E-06

37 r3

6.476E-05

4.215E-06

38 r1

0.0036565

2.311E-05

0.0036565

2.311E-05

39 SstBT

1.842371

1.842371

3.814967

3.376728

PARTE D
T
600
650
700
750
800
825
850
875
900
925
950
975
1000
1015
1020
1025

Fst
4.17E-06
1.92E-05
6.76E-05
0.0001925
0.0004555
0.0006554
0.0009022
0.0011876
0.0014935
0.0017913
0.0020441
0.0022117
0.0022604
0.002226
0.0022042
0.0021777

T
1030
1040
1060
1070
1080
1090
1100
1110
1115
1120
1125
1130
1135
1140
1145

Fst
0.0021468
0.0020733
0.001894
0.0017951
0.0016853
0.0015408
0.0013172
0.0009705
0.0007368
0.0006813
0.000802
0.0009258
0.0008264
0.0010953
0.0010536

La curva anterior tienes esta apariencia por ser de grado 3, ya que al plotear en el polymath fue la
que mejor se acerco dentro de sus parametros establecidos, porque al probar entre grado uno y
dos estos datos se encuentran muy distorcionados.
PARTE E
Relacin
10
14
18
22
23
24
25
26
27
28
29
30
34
38
42

Fst
0.0014064
0.0016311
0.0017601
0.0018129
0.0018181
0.0018208
0.0018214
0.0018203
0.0018175
0.0018134
0.0018081
0.0018018
0.0017688
0.0017277
0.0016823

Relacin
46
50
54
58
62
66
70
74
78
82
86
90
94
98
100

Fst
0.001635
0.0015872
0.0015398
0.0014935
0.0014485
0.0014051
0.0013633
0.0013233
0.0012849
0.0012483
0.0012133
0.0011798
0.0011479
0.0011174
0.0011027

PARTE F: con intercambiador de calor la temperatura sugerida es 1028K

PH = (Fto * R * T / vo) * FH / Ft
Pst = (Fto * R * T / vo) * FeB / Ft
Ft = FeB + FH + FB + Fst + FT + Fm + Fet + Fi
Fto = 0.00344 + Fi
Fi = 19 * 0.00344
Kp1 = exp(-17.34 + -1.302 * 10 ^ 4 / T + 5.051 * ln(T) + ((-2.314 * 10 ^ -10 * T + 1.302 * 10 ^ -6) * T
+ -4.931 * 10 ^ -3) * T) # atm
CpeB = -43.1 + 0.7072 * T - 0.0004811 * T ^ 2 + 1.301 * 10 ^ -7 * T ^ 3
CpH = 27.14 + 0.009274 * T - 0.00001381 * T ^ 2 + 7.645 * 10 ^ -9 * T ^ 3
CpB = -33.92 + 0.4739 * T - 0.0003017 * T ^ 2 + 7.13 * 10 ^ -8 * T ^ 3
Cpst = -28.25 + 0.6159 * T - 0.0004023 * T ^ 2 + 9.935 * T ^ 3 * 10 ^ -8
CpT = -24.35 + 0.5125 * T - 0.0002765 * T ^ 2 + 4.911 * 10 ^ -8 * T ^ 3
Cpm = 19.25 + 0.05213 * T + 0.00001197 * T ^ 2 - 1.132 * 10 ^ -8 * T ^ 3
Cpet = 3.806 + 0.1566 * T - 0.00008348 * T ^ 2 + 1.755 * 10 ^ -8 * T ^ 3
Cpi = 32.24 + 0.001924 * T + 0.00001055 * T ^ 2 - 3.596 * 10 ^ -9 * T ^ 3
Ua = 100 / 60 # kJ/m3.s.K
DH1eB = int1 + 117690
int1 = 41.99 * T - 0.082026 * T ^ 2 / 2 + 6.499 * 10 ^ -5 / 3 * T ^ 3 - 2.3105 * 10 ^ -8 / 4 * T ^ 4
DH2eB = int2 + 105510
int2 = 12.986 * T - 0.0767 / 2 * T ^ 2 + 0.00009592 / 3 * T ^ 3 - 4.125 * 10 ^ -8 / 4 * T ^ 4
DH3eB = int3 - 54680
int3 = 10.86 * T - 0.151844 / 2 * T ^ 2 + 0.00023038 / 3 * T ^ 3 - 9.9955 * 10 ^ -8 / 4 * T ^ 4
d(T)/d(v) = (Ua * (Ta - T) + (-DH1eB * r1 - DH2eB * r2 - DH3eB * r3)) / (FeB * CpeB + FH * CpH +
FB * CpB + Fst * Cpst + FT * CpT + Fm * Cpm + Fet * Cpet + Fi * Cpi)
T(0) = 1028
R = 0.082057 # m3.atm/kmol.K
vo = Ft * R * T / P
v(0) = 0

v(f) = 10
P = 2.4 # atm
SstBT = r1 / (r2 + r3)
Ta = 1000

Calculated values of DEQ variables

Variable Initial value Minimal value Maximal value Final value
1

10.

10.

FeB

0.00344

1.093E-06

0.00344

1.093E-06

FB

0.0009398

0.0009398

FH

0.0022482

0.0022482

Fst

0.0023736

0.0023736

FT

0.0001254

0.0001254

Fm

0.0001254

0.0001254

Fet

0.0009398

0.0009398

1028.

963.9904

1028.

997.3838

10 P

2.4

2.4

2.4

2.4

11 Fi

0.06536

0.06536

0.06536

0.06536

12 Ft

0.0688

0.0688

0.0721135

0.0721135

13 p

2137.

2137.

2137.

2137.

14 phi

0.4

0.4

0.4

0.4

15 Fto

0.0688

0.0688

0.0688

0.0688

16 R

0.082057

0.082057

0.082057

0.082057

17 vo

2.418165

2.34419

2.45914

2.45914

18 Pst

0.12

3.47E-05

0.12

3.47E-05

19 PeB

0.12

3.47E-05

0.12

3.47E-05

20 PH

0.0713851

0.0713851

21 Kp1

2.946636

1.11491

2.946636

1.879859

22 CpeB

316.8201

308.1051

316.8201

312.7454

23 CpH

30.38481

30.09525

30.38481

30.23706

24 CpB

211.8759

206.4242

211.8759

209.3586

25 Cpst

287.6822

280.6233

287.6822

284.4132

26 CpT

263.651

256.7441

263.651

260.4796

27 Cpm

73.19159

70.48595

73.19159

71.91968

28 Cpet

95.63633

92.91266

95.63633

94.36515

29 Cpi

41.46034

40.67733

41.46034

41.08599

30 Ua

1.666667

1.666667

1.666667

1.666667

31 int1

1.691E+04

1.678E+04

1.691E+04

1.686E+04

32 DH1eB

1.346E+05

1.345E+05

1.346E+05

1.345E+05

33 int2

-3959.984

-3959.984

-3382.722

-3679.535

34 DH2eB

1.016E+05

1.016E+05

1.021E+05

1.018E+05

35 int3

-1.355E+04

-1.355E+04

-1.287E+04

-1.323E+04

36 DH3eB

-6.823E+04

-6.823E+04

-6.755E+04

-6.791E+04

37 r2

0.0023725

3.252E-07

0.0023725

3.252E-07

38 r3

4.917E-05

6.929E-08

39 r1

0.0034247

6.875E-07

0.0034247

6.875E-07

40 SstBT

1.443462

1.443462

2.721658

1.742717

41 Ta

1000.

1000.

1000.

1000.

PARTE G
El objetivo del problema es aplicar obtener los distintos flujos y relaciones de selectividad,
mediante un programa (POLYMATH) de modo que al finalizarlo podamos saber que comandos
utilizar y que forma darle a nuestra ecuacin.