DIFERENCIAL NUMERICO

C(M)
0
1
2
3
4
5
6
7
8
9
10

Cprom
1
0.67
0.5
0.4
0.33
0.29
0.25
0.22
0.2
0.18
0.17

Vprom
0.835
0.585
0.45
0.365
0.31
0.27
0.235
0.21
0.19
0.175

ln Cprom
-0.33
-0.17
-0.1
-0.07
-0.04
-0.04
-0.03
-0.02
-0.02
-0.01

-0.18032355
-0.53614343
-0.7985077
-1.00785793
-1.17118298
-1.30933332
-1.44816976
-1.56064775
-1.66073121
-1.74296931

ln Vprom
-1.10866262
-1.77195684
-2.30258509
-2.65926004
-3.21887582
-3.21887582
-3.5065579
-3.91202301
-3.91202301
-4.60517019

DEA UERDO A LA ECN DE LA RECTA SE OBTIENEN LOS VALORES

-2
Axis Title

t(min)

y = 2.0654x

ln Vprom
0
-1.5

-1

-0.5

y = 2.0654x - -1
0.6638 -2
R = 0.978 -3
-4
Axis Title

-5

ln Vprom
Linear (ln Vprom)

METODO INTEGRAL GRAFICO (p

PROBANDO

= 0.
x

y
t
0
1
2
3
4
5
6
7
8
9
10

CA
1
0.55
0.3
0.17
0.09
0.05
0.03
0.01
0.01
0
0

CA ^0.5
1
0.74161985
0.54772256
0.41231056
0.3
0.2236068
0.17320508
0.1
0.1

= 1
y
t
0
1
2
3
4
5
6
7
8
9
10

CA
1
0.67
0.5
0.4
0.33
0.29
0.25
0.22
0.2
0.18
0.17

ln CA
0
-0.40047757
-0.69314718
-0.91629073
-1.10866262
-1.23787436
-1.38629436
-1.51412773
-1.60943791
-1.71479843
-1.77195684

Chart Title
0
0
-0.5
LN CA

-1
-1.5

4
6
y =2 -0.1914x
-8
0.2194
R = 0.9512

-2

TIEMPO

= 2
y
t
0
1
2
3
4

CA
1
0.67
0.5
0.4
0.33

1/CA
1
1.49253731
2
2.5
3.03030303

Chart Title
5
4
Axis Title

y = 10.783x - 26.465
R = 0.6268

10

0.29
0.25
0.22
0.2
0.18
0.17

3.44827586
4
4.54545455
5
5.55555556
5.88235294

Axis Title

5
6
7
8
9
10

R = 0.6268

3
2
1
0
0

Axis Title

10

EGRAL GRAFICO (prueba y error)

= 0.5
Chart Title
1.2

Axis Title

1
0.8
0.6

Series1

0.4

y = -0.1077x + 0.8307
0
R2 = 0.9026
0
4
6

Linear (Series1)

0.2

-0.2

10

Axis Title

= 1.5

Series1
Linear (Series1)

y
t
0
1
2
3
4
5
6
7
8
9
10

CA
1
0.67
0.5
0.4
0.33
0.29
0.25
0.22
0.2
0.18
0.17

CA^-0.5
1
1.22169444
1.41421356
1.58113883
1.74077656
1.85695338
2
2.13200716
2.23606798
2.3570226
2.42535625

Chart Title
2.5
2

Axis Title

1.5

y 1= 1.1983x - 0.3289
0.5
R = 0.8872
0
0

4
Axis Title

Series1
Linear (Series1)

.5
Chart Title

- 0.3289
= 0.8872
4

Axis Title

Series1
Linear (Series1)
8

10

INTEGRAL NUM
SE PUEDE SABRER EL RODEN Y LA KCIN
SI LAS K SON IGUALES EL ORDEN ES EL CORRESPONDIENTE Y LA K IGUAL

= 1
t

CA0 INICIAL SIMPRE

K= (1/t)(ln(Cao/Ca))

CA
0
1
2
3
4
5
6
7
8
9
10

= 1.5

1
0.67
0.5
0.4
0.33
0.29
0.25
0.22
0.2
0.18
0.17

0.400477567
0.34657359
0.305430244
0.277165656
0.247574871
0.23104906
0.216303962
0.201179739
0.190533159
0.177195684

CA
0
1
2
3
4
5
6
7
8
9
10

1
0.67
0.5
0.4
0.33
0.29
0.25
0.22
0.2
0.18
0.17

INTEGRAL NUMERICO

= 1.5

= 2

CA0 INICIAL SIMPRE

K= (1/0.55t) (1/CA^0.55 - 1/CA0^0.55)
0.443388887
0.414213562
0.387425887
0.37038828
0.342781353
0.333333333
0.323430618
0.309016994
0.301560579
0.28507125

CA
0
1
2
3
4
5
6
7
8
9
10

1
0.67
0.5
0.4
0.33
0.29
0.25
0.22
0.2
0.18
0.17

se despeja k de la ecn. De velocidad integrada

de acuerdo al ejercicio anterior

= 2
CA0 INICIAL SIMPRE
K= (1/t)(1/CA - 1/CA0)
0.492537313
0.5
0.5
0.507575758
0.489655172
0.5
0.506493506
0.5
0.50617284
0.488235294

METODO DE VIDA MEDIA

cuando ya nos da los tiempos de vida media, de lo contrario hacer grafica a mano.
t 1/2
82.5
139
296
360

850
470
255
212

ln C N2O
4.41279829
4.93447393
5.69035945
5.88610403

ln t 1/2
6.745236349
6.152732695
5.541263545
5.356586275

8
7

y = -0.9211x + 10.767
R = 0.9941

6
Axis Title

C N2O

5
4
3
2
1
0
0

4
Axis Title

ln t 1/2

.9211x + 10.767
R = 0.9941
ln t 1/2
Linear (ln t 1/2)

4
Axis Title

ENERGIA DE ACTIVACIN
T(K)
20
30
40
50
60
70
80

K
293
303
313
323
333
343
353

1.00E-04
3.35E-04
1.41E-03
3.06E-03
8.13E-03
2.11E-02
5.01E-02

1/T
ln K
0.00341297
-9.210340372
0.00330033
-8.001380026
0.00319489
-6.564165575
0.00309598
-5.789340363
0.003003
-4.812194355
0.00291545
-3.858482239
0.00283286
-2.993734271

0
0

0.001

-2
Axis Title

T (C)

-4
-6
-8
-10

y = -10630x + 27.1
R = 0.9974

Chart Title
0.001

0.002

0.003

0.004

Series1
Linear (Series1)

-10630x + 27.148
R = 0.9974
Axis Title