Nama :

Ridhani Rida Ramadhan

Dian Nita Citra Dewi
Alfunsina AAT
Dwi Chandra Pujayanti

(115061100111009)
(115061101111013)

Soal !!
1. The CO in a 20.3 L sample of gas was converted to CO2 by passing the gas over
iodine pentoxide heated to 150oC, and I2 was distilled and collected to 8.25 mL of
0.01101 M Na2S2O3. Then back titration with 2.16 mL of 0.00947 M I2 solution.
Calculate the mg of CO per liter of sample.
2. A 100 mL sample of brackish water was made ammonical, and the sulfide it
contained was titrated with 16.47 mL of 0.0231 M AgNO3. Calculate [H2S] in the
water in ppm.
3. Sketch titration curves for 50 mL of 0.04 M H3PO4 with 0.12 M NaOH.

Pembahasan Soal !!
1.
Diketahui
:
V total sampel =20,3 liter
5CO(g) + I2O5(s) 5CO2(g) + I2(g)
Back titration
I2 + 2Na2S2O3 2NaI + Na2S4O6
n mula-mula Na2S2O3
= 8,25 ml x 0,01101 M
n mula-mula I2
= 2,16 ml x 0,00947 M

= 0,0908325 mmol
= 0,0204552 mmol

Ditanya
:
mg CO per Liter sampel??
Jawab :

M
R
S

I2 +
0,0204552
0,0204552
-

Massa CO

2Na2S2O3 2NaI + Na2S4O6

0,0908325
0,0409104
0,0409104
0,0499221
0,0409104

=( 5/2 x 0,0499221 mmol )x (12+16 mg/mmol)

= 3,494547 mg

Massa CO per liter of sample = 3,494547 mg / 20,3 L

= 0,172 mg/L

2.

Diketahui
:
V Sampel
= 100 ml = 0,1 L
n AgNO3
= 0,380457 mmol
Ditanya
:
[H2S] in the water in ppm?
Jawab
:
+
2Ag + S2- Ag2S
mol H2S
= 0,380457 mmol AgNO3 x 1 mmol H2S / 2 mmol AgNO3
= 0,1902285 mmol H2S
massa H2S
= 0,1902285 mmol H2S x 34 mg/mmol
= 6,468 mg H2S
[H2S](mg/L) = 6,468 mg H2S / 0,1 L sampel
= 64,68 mg/L
= 64,68 ppm
3.
Diketahui
:
Ka1 H3PO4 = 7,1 x 10-3
V H3PO4
= 50 ml
M H3PO4
= 0,0231 M
M NaOH
= 0,12
H3PO4 + NaOH NaH2PO4 + H2O
Ditanya
:
Kurva titrasi H3PO4 dengan NaOH.
Jawab :
V titran saat eqivalen
M V(H3PO4)
= M V (NaOH)
2 mmol
= 0.12 V
V NaOH
= 16.667 ml
pH sebelum eqivalen
pada penambahan V NaOH 15 ml
H3PO4 +
NaOH
NaH2PO4 + H2O
M
2 mmol
1,8 mmol
R
1,8 mmol
1,8 mmol
1,8 mmol
S
0,2 mmol
1,8 mmol
+
[H ] = Ka [Asam]/[Garam]
= 7,1x10-3 x 0.0030769 / 0,0276923
=0.000789
pH
= -log(0,000789)=3,1029
pH sesudah eqivalen
pada penambahan V NaOH 17 ml
H3PO4 +
NaOH
NaH2PO4 + H2O
M
2 mmol
2,04 mmol
R
2 mmol
2 mmol
2 mmol
S
0,04 mmol
2 mmol
[NaOH]
= 0,04 / (50+17) = 0,000597
pH
= 14-(- log(0,000597))=10,77598
pH saat eqivalen
penambahan pada V NaOH 16,667 ml
H3PO4 +
NaOH
NaH2PO4 + H2O
M
2 mmol
2 mmol

R
S

2 mmol
-

2 mmol
-

[OH-] =

2 mmol
2 mmol
=0,2056 x 10-6
Kurva titrasi asam phospat dengan NaOH

pH

pH
= 14-(6-log(0,2056))=7,313
v basa
pH
10
2.32483
13
11
2.43681
12
11
12
2.55892
10
13
2.69841
9
8
14
2.8689
7
15
3.10298
6
16.6667 7.31293
5
4
17
10.776
3
18
11.3716
2
19
11.6083
1
0
20
11.757
9
10
21
11.8647

titik ekivalen

11

12

13

14
15 NaOH
16 (ml)17
Volume

18

19

20

21

22

Grafik pada Ka 2 =6,3 x 10-8

pH
7.37675
7.48872
7.61083
7.75033
7.92082
8.1549
9.83889
10.776
11.3716
11.6083
11.757
11.8647

Kurva titrasi asam phospat dengan NaOH

13
12
11
10

titik ekivalen

9
8

pH

v basa
10
11
12
13
14
15
16.6667
17
18
19
20
21

7
6
5
4
3
2
1
0
9

10

11

12

13

14
15
16
17
Volume NaOH (ml)

18

19

20

21

22

Grafik pada Ka 3=4,5 x 10-13

Kurva titrasi asam phospat dengan NaOH
pH
13.0669
13.301
12.412
10.776
11.3716

14
13
12
11
10
9
8
7
6
5
4
3
2
1
0

titik ekivalen

pH

V basa
14
15
16.6667
17
18

10

11

12
Volume NaOH (ml)

13

14

15