Soal dan Jawaban !

1.

The CO in a 20.3 L sample of gas was converted to CO2 by passing the gas
over iodine pentoxide heated to 150oC, and I2 was distilled and collected
to 8.25 mL of 0.01101 M Na2S2O3. Then back titration with 2.16 mL of
0.00947 M I2 solution. Calculate the mg of CO per liter of sample.

I2O5(s) + 5CO(g) 5CO2(g) + I2(g)

Dan setelah itu I2 dititrasi dengan Na2S2O3
I2(aq) + 2S2O32-(aq) 2I-(aq) + S4O62-(aq)
Mula mula
0,0204552
0,0908325
Reaksi
0,0204552
0,0409104
0,0409104
-----------------------------------------------------------------------------------------Setimbang
0,0499221
0,0409104

Mol Na2S2O3 Sisa = 0,0499221 mmol

= 4,99221 x 10-5 mol
Massa CO = ( 5/2 x 4,99221 x 10-5 mol)x (12+16 g/mol)
= 3,494547 x 10-3 g
= 3,494547 mg
Massa CO per liter sampel

= 3,494547 mg / 20,3 L
= 0,172 mg/L

2. A 100 mL sample of brackish water was made ammonical, and the sulfide it contained
was titrated with 16.47 mL of 0.0231 M AgNO3. Calculate [H2S] in the water in ppm.

2Ag+ + S2- Ag2S

mol H2S
massa H2S
[H2S](mg/L)

= 0,380457 mmol AgNO3 x 1 mmol H2S / 2 mmol AgNO3

= 0,1902285 mmol H2S
= 0,1902285 mmol H2S x 34 mg/mmol
= 6,468 mg H2S
= 6,468 mg H2S / 0,1 L sampel
= 64,68 mg/L
= 64,68 ppm

3. Sketch titration curves for 50 mL of 0.04 M H3PO4 with 0.12 M NaOH.

Diketahui :
Ka1 H3PO4
V H3PO4
M H3PO4
M NaOH

= 7,1 x 10-3
= 50 ml
= 0,0231 M
= 0,12 M

(I) V titran saat eqivalen

M V(H3PO4) = M V (NaOH)
2 mmol
= 0.12 V
V NaOH
= 16.667 ml

(II) pH sebelum eqivalen

pada penambahan V NaOH 15 ml
H3PO4 + NaOH NaH2PO4 + H2O
M
2 mmol 1,8 mmol
R
1,8 mmol 1,8 mmol 1,8 mmol
S
0,2 mmol 1,8 mmol
[H+]

= Ka [Asam]/[Garam]
= 7,1x10-3 x 0.0030769 / 0,0276923
=0.000789

pH

= -log(0,000789)=3,1029

(III) pH sesudah eqivalen

pada penambahan V NaOH 17 ml
H3PO4 + NaOH
NaH2PO4 + H2O
M
2 mmol 2,04 mmol
R
2 mmol 2 mmol
2 mmol

0,04 mmol

2 mmol

[NaOH] = 0,04 / (50+17) = 0,000597

pH
= 14-(- log(0,000597))=10,77598
(IV) pH saat eqivalen
penambahan pada V NaOH 16,667 ml
H3PO4 + NaOH NaH2PO4 + H2O
M
2 mmol 2 mmol
R
2 mmol 2 mmol 2 mmol

[OH-]
pH

= ==0,2056 x 10-6
= 14-(6-log(0,2056))=7,313

2 mmol

v basa

pH

10

2.32483

11

2.43681

12

2.55892

13
12
11

2.69841

14

2.8689

15

3.10298

16.6667

7.31293

17

10.776

18

11.3716

19

11.6083

10
9
pH

13

titik ekivalen

7
6
5
4
3
2
1

20

11.757

0
9

21

11.8647

10

11

12

13

14

15

16

17

Volume NaOH (ml)

18

19

20

21

22

Grafik pada Ka 2 =6,3 x 10-8

v basa

pH

10

7.37675

11

7.48872

12

7.61083

13

7.75033

14

7.92082

15

8.1549

16.6667

9.83889

17

10.776

18

11.3716

19

11.6083

20

11.757

21

11.8647

13
12
11
10

titik ekivalen

9
pH

8
7
6
5
4

3
2
1
0
9

10

11

12

13

14

15

16

17

Volume NaOH (ml)

18

19

20

21

22

Grafik pada Ka 3 =4,5 x 10-13

Kurva titrasi asam phospat dengan NaOH

V basa

pH

14
13

titik ekivalen

12

14

13.0669

11
10

13.301

pH

15

8
7

16.6667

12.412

5
4
3

17

10.776

2
1

18

11.3716

0
9

10

11

12
Volume NaOH (ml)

13

14

15