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  • Highopne

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    mekanic24
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    Biodiesel is more susceptible to oxidation during long-term storage than conventional diesel due to its chemical composition. Fatty acid methyl esters in biodiesel are more sensitive to oxidative degradation, especially those with high contents of polyunsaturated esters. The methylene groups next to double bonds in these esters are vulnerable to radical attack, which initiates the fuel oxidation process. The hydroperoxides formed from oxidation may polymerize into insoluble sediments and gums that clog filters.

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    Biodiesel is more susceptible to oxidation during long-term storage than conventional diesel due to its chemical composition. Fatty acid methyl esters in biodiesel are more sensitive to oxidative degradation, especially those with high contents of polyunsaturated esters. The methylene groups next to double bonds in these esters are vulnerable to radical attack, which initiates the fuel oxidation process. The hydroperoxides formed from oxidation may polymerize into insoluble sediments and gums that clog filters.

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    27 visualizzazioni1 pagina

    Highopne

    Caricato da

    mekanic24
    Biodiesel is more susceptible to oxidation during long-term storage than conventional diesel due to its chemical composition. Fatty acid methyl esters in biodiesel are more sensitive to oxidative degradation, especially those with high contents of polyunsaturated esters. The methylene groups next to double bonds in these esters are vulnerable to radical attack, which initiates the fuel oxidation process. The hydroperoxides formed from oxidation may polymerize into insoluble sediments and gums that clog filters.

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    biodiesel makes it more susceptible to oxidation or auto-oxidation during long-term storage than conventional petrodiesel.

    Due to their chemical composition, fatty acid methyl esters are more sensitive to oxidative degradation than fossil diesel fuel especially those esters containing a high content of twice and morefold unsaturated esters, as the methylene groups adjacent to double bonds have turned out to be particularly susceptible to radical attack as the first step of fuel oxidation (Knothe, 2006).
    Lauric acid 61.1 Myristic acid 69.9 Palmitic acid 74.4 Stearic acid 76.3 Oleic acid 57.2 Linoleic acid 36.8 Linolenic acid 21.6 Table 5: Cetane number (CN) of pure fatty acid methyl esters
    Source: Bangboye and Hansen (2008).

    The formed hydroperoxides may polymerise with other free radicals to form insoluble sediments and gums, which are associated with fuel filter

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