PRODUCT #: 329541 NAME: DICUMYL PEROXIDE, 98% MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98 Printed Thursday,

March 20, 1903 11:29AM Sigma Chemical Co. P.O. Box 14508 St. Louis, MO 63178 Phone: 314-771-5765 Aldrich Chemical Co., Inc. 1001 West St. Paul Milwaukee, WI 53233 Phone: 414-273-3850 Fluka Chemical Corp. 1001 West St. Paul Milwaukee, WI 53233 Phone: 414-273-3850

SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - CATALOG #: 329541 NAME: DICUMYL PEROXIDE, 98% SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - CAS #: 80-43-3 MF: C18H22O2 EC NO: 201-279-3 SYNONYMS ACTIVE DICUMYL PEROXIDE * BIS(ALPHA,ALPHA-DIMETHYLBENZYL)PEROXIDE * CUMENE PEROXIDE * CUMYL PEROXIDE * DICUMYL PEROXIDE * DI-ALPHA-CUMYL PEROXIDE * DI-CUP * DI-CUP 40 KE * DI-CUPR * DIISOPROPYLBENZENE PEROXIDE * ISOPROPYLBENZENE PEROXIDE * LUPEROX 500R * LUPEROX 500T * PEROXIDE, BIS(1-METHYL-1-PHENYLETHYL) * VAROX DCP-R * VAROX DCP-T * SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - LABEL PRECAUTIONARY STATEMENTS OXIDIZING IRRITANT MAY CAUSE FIRE. IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. KEEP AWAY FROM COMBUSTIBLE MATERIAL. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION. REFRIGERATE. SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE. SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - EXTINGUISHING MEDIA WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. SPECIAL FIREFIGHTING PROCEDURES WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. ORGANIC PEROXIDE. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. UNUSUAL FIRE AND EXPLOSIONS HAZARDS EMITS TOXIC FUMES UNDER FIRE CONDITIONS. CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS. ADDITIONAL INFORMATION RAPID DECOMPOSITION MAY OCCUR AT TEMPERATURES ABOVE 82 C. SELF Page 1

PRODUCT #: 329541 NAME: DICUMYL PEROXIDE, 98% MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98 Printed Thursday, March 20, 1903 11:29AM ACCELERATING DECOMPOSITION TEMPERATURE IS 93 C. SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNITION. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. USE NONSPARKING TOOLS. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - REFER TO SECTION 8. SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - CHEMICAL SAFETY GOGGLES. COMPATIBLE CHEMICAL-RESISTANT GLOVES. NIOSH/MSHA-APPROVED RESPIRATOR. SAFETY SHOWER AND EYE BATH. MECHANICAL EXHAUST REQUIRED. DO NOT BREATHE DUST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING. IRRITANT. KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - APPEARANCE AND ODOR WHITE CRYSTALLINE SOLID PHYSICAL PROPERTIES MELTING POINT: 39 C TO 41 C FLASHPOINT >230 109C VAPOR PRESSURE: 15.4MM 38 C VAPOR DENSITY: 9.3 SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - STABILITY UNSTABLE. CONDITIONS TO AVOID HEAT CHEMICAL CONTAMINATION KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. INCOMPATIBILITIES STRONG ACIDS STRONG BASES STRONG OXIDIZING AGENTS HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE METHANE GAS PHENOL ACETOPHENONE CUMYL ALCOHOL HAZARDOUS POLYMERIZATION WILL NOT OCCUR. SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - ACUTE EFFECTS MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. CAUSES EYE AND SKIN IRRITATION. Page 2

PRODUCT #: 329541 NAME: DICUMYL PEROXIDE, 98% MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98 Printed Thursday, March 20, 1903 11:29AM MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. PROLONGED OR REPEATED INHALATION MAY CAUSE CONGESTION AND RHINITIS. RTECS #: SD8150000 PEROXIDE, BIS(ALPHA,ALPHA-DIMETHYLBENZYL) TOXICITY DATA ORL-RAT LD50:4100 MG/KG BSPII* 1/75-19B UNR-RAT LD50:3500 MG/KG 34ZIAG -,655,1969 ADDITIONAL INFORMATION ORL-RAT LD50:4100 MG/KG IHL-RAT LC50:>224 MG/KG ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - DATA NOT YET AVAILABLE. SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - EUROPEAN INFORMATION EC INDEX NO: 617-006-00-X OXIDIZING IRRITANT R 7 MAY CAUSE FIRE. R 36/38 IRRITATING TO EYES AND SKIN. S 3/7 KEEP CONTAINER TIGHTLY CLOSED IN A COOL PLACE. S 14 KEEP AWAY FROM... S 36/37/39 WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION. REVIEWS, STANDARDS, AND REGULATIONS OEL=MAK NOHS 1974: HZD 80273; NIS 7; TNF 256; NOS 25; TNE 5641 NOES 1983: HZD 80273; NIS 11; TNF 606; NOS 26; TNE 17958; TFE 8122 EPA TSCA SECTION 8(B) CHEMICAL INVENTORY SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH, FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE. COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC., FLUKA CHEMIE AG LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY

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