Analytical Chemistry

1. Exactly 750.0 mL of a solution that contained 480.4 ppm of Ba(NO 3)2 were mixed with 200.0 mL of a solution that was 0.03090 M in Al2(SO4)3. A. What mass of solid BaSO4 was formed? B. What was the molarity of the unreacted reagent [Al2(SO4)3 or Ba(NO3)2 ]? 2. What mass of MgNH4PO4 precipitated when 200.0 mL of a 1.000% (W/V) solution of MgCl2 were treated with 40.0 mL of 0.1753 M Na3PO4 and an excess of NH4+? What was the molarity of the excess reagent (Na3PO4 or MgCl2) after the precipitation was complete? 3. Exactly 25.0 mL of a 0.3757 M solution of Na3PO4 were mixed with 100.0 mL of 0.5151 M HgNO3. A. What mass of solid Hg3PO4 was formed? B. What is the molarity of the unreacted species (Na3PO4 or HgNO3) after the reaction was completed? 4. What volume of 0.01000 M AgNO3 would be required to precipitate all of the I- in 200.0 mL of a solution that contained 24.32 ppt KI? 5. What mass of solid PbCl2 (278.10 g/mol) is formed when 200 mL of 0.125 M Pb2+ are mixed with 400mL of 0.175 M Cl-?

BS Mining Engineering 1