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c
-x
+x
+x
e
0.10 x
x
x
Ka =
][
= 1.8 x 10-5
x = 1.33 x 10-3 M
pH = -log [1.33 x 10-3]
pH = 2.88
Solution 2 HoAc OAc
na + nb = nbuffer
= 0.05 M (0.10 L)
na + nb = 0.005 mol
pH = 5
pH = pKa + log
5 = 4.74 + log
log
= 0.026
= 1.82
na + 1.82na = 0.005 mol
na = 1.77 x 10-3 mol
nb = 3.23 x 10-3 mol
c
-x
+x
+x
e
0.10 x
x
x
Kb =
= 1.8 x 10-5
x = 1.33 x 10-5 M
pOH = -log [1.33 x 10-5]
pOH = 2.88
pH = 11.12
= 0.026
= 1.82
nb + 1.82nb = 0.005 mol
nb = 1.77 x 10-3 mol
na = 3.23 x 10-3 mol
Solution 1- HoAc
*Acid Addition
15 ml 0.10 M CH3COOH + 0.1 ml 1 M HCl
CH3COOH +
H 2O
CH3COO- +
i
c
e
+x
x
-x
Ka =
][
x = 2.59 x 10-4 M
pH = -log [
pH = 2.16
+x
= 1.8 x 10-5
=
2.59 x 10-4]
H3O+
*Base Addition
15 ml 0.10 M CH3COOH + 0.1 ml 1 M NaOH
CH3COOH +
OH-
CH3COO- + H2O
i
c
+
0
(
pH = 3.59
Solution 2 HOAC-OAC*Acid Addition
(
pH = 4.96
*Base Addition
(
(
pH = 5.04
Solution 3- NH3
* Acid Addition
15 ml 0.10 M NH3 + 0.1 ml 1 M HCl
NH3 +
H+
NH4+
i
c
+
0
pOH = 3.59
pH = 10.41
*Base Addition
15 ml 0.10 M NH3 + 0.1 ml 1 M NaOH
NH3
+ H2O NH4+ +
OHi
c
-x
+x
+x
e
x
Kb =
][
x = 2.59 x 10-4 M
pOH = -log [
pOH = 2.16
pH = 11.84
= 1.8 x 10-5
2.59 x 10-4]
pOH = 5.04
pH= 8.96
*Base Addition
(
(
pOH = 4.96
pH = 9.04
ANSWERS TO QUESTIONS
1.
0.10 M HoAc Oac pH = 5.5
0.20 moles HoAc + 0.50 mol NaOH
nT = 0.75 (0.10) = 0.75na + nb
5.5 = 4.74 + log nb / na
nb / na = 5.75
nb = 5.75na
0.75 mol = na + 5.75na
0.75 mol = 6.75na
nb = 0.11 VOAc = 0.22 L
na = 0.64 VHoAc = 0.64 L
2.
4.
6. pH of 50 ml 0.10 M HCO3- = 5.66
*Acid Addition
50ml 0.10 M HCO3- + 0.1 ml 1 M HCl
HCO3+
H2O
CO32- +
i
c
e
+x
x
-x
Ka =
][
[
H3O+
]
]
= 1.8 x 10-5
x = 2.35 x 10-9 M
pH = -log [
pH = 2.70
+x
= 2.35 x 10-9]
*Base Addition
50ml 0.10 M HCO3- + 0.1 ml 1 M NaOH
HCO3+
OH-
CO32-
i
c
e
+
0
(
H2O
pH = 6.43