KarenFounk,ShannonMendes

Curriculum Topic Review

SCH4U Energy Changes and Rates of Reaction
Activity: Using Bingo to Review Formula: Q=cmT

Ministry Expectations
o D2.1 use appropriate terminology related to energy changes and rates of reaction,
including, but not limited to: enthalpy, activation energy, endothermic, exothermic,
potential energy, and specific heat capacity [C]
o D2.3 Solve problems involving analysis of heat transfer in a chemical reaction, using the
equation Q = mcT (e.g., calculate the energy released in the combustion of an organic
compound, and express the results in energy per mole of fuel [J/mol]) [AI, C]
Learning Goals
o Students will review key terms (exo/endothermic, enthalpy, specific heat capacity, etc)
o Students will write thermochemical equations, expressing the energy changes as a H
value or as a heat term in the equation
o Students will work together to solve problems using Q=cmT
Teacher Instructions
1. Divide students into bingo families/teams (6 people per group):
o Distribute cards to students (Appendix A)
o Ask students to get into groups based on the category of enthalpy change
represented on the card they received.
o E.g., students could form 1 group based on the theme of combustion:
Molar Enthalpy of Combustion
Hocomb
C4H10(g)+13/2O2(g)>4CO2(g)+5H2O(l)+2871kJ
C4H10(g)+13/2O2(g)>4CO2(g)+5H2O(l) Ho=2871kJ
Enthalpychangewhen1molofsubstanceiscompletelyburnedinO2.
Theburningofwood
2. Guide students as they review key concepts using bingo:
Distribute bingo instructions, questions and cards to students (Appendix B-C)
Ask one member from each team to close their eyes and randomly pick a question
Students will read out question to bingo family and solve question as a team
Once the question is solved, students will look for the answer on their BINGO
sheet and put the number of the question in the box with the answer
o The aim of the game is to get four boxes in a row, horizontally, vertically or
diagonally
o
o
o
o

KarenFounk,ShannonMendes

Appendix A: Cards for Sorting Students into Bingo Groups

MolarEnthalpyofCombustion

Enthalpychangewhen1moleofa
substanceiscompletelyburnedinoxygen

Hocomb

E.g.Theburningofwood

C4H10(g)+13/2O2(g)4CO2(g)+5H2O(l)+
2871kJ

Hocomb=2676kJ/molbutanol

MolarEnthalpyofFormation

Hof

2C(s)+3H2(g)+O2(g)C2H5OH(l)+235
kJ

Enthalpychangefortheformationofone
moleofacompoundfromitselements

C(s)+2H2(g)+O2(g)CH3OH(l)
Hof=239.1kJ

Hof=1273.1kJ/molglucose

KarenFounk,ShannonMendes

MolarEnthalpyofSolution

Enthalpychangewhen1moleofasoluteis
dissolvedinasolvent

Hosol

E.g.Thetemperaturedrops5oCwhen7.46g
ofKClisdissolvedin100.0mL

KCl(s)+17kJK+(aq)+Cl(aq)

KCl(s)K+(aq)+Cl(aq)Hosol=+17kJ

MolarEnthalpyofNeutralization

Enthalpychangewhen1moleofacidis
neutralized

Ho

neut=57.5kJ/molNaOH

NaOH(aq)+H2SO4(aq)
Na2SO4(aq)+H2O(l)+57.5kJ

Thetemperatureriseswhen10.0mLof
1.0MNaOHisaddedto10.0mLof1.0M
H2SO4
NaOH(aq)+H2SO4(aq)
Na2SO4(aq)+H2O(l)

Honeut=57.5kJ

KarenFounk,ShannonMendes

Appendix B: Bingo Questions (Teacher copy)

1. Whatisthetemperaturechangeofa120gpieceofaluminumwhosespecificheatis
1.89J/gCafter1800Jofheatenergyisapplied?

1800=120x1.89xT
T=7.94oC

2. 1.0gofsodiumhydroxide,NaOH,wasaddedto99.0gofwater.Thetemperatureof
thesolutionincreasedfrom18.0to20.5oC.Thespecificheatcapacityofthesolution
is4.18Jg1K1.WhichexpressiongivestheheatevolvedinkJmol1?

A. (2.5x100.0x4.18x1000)
40.0

B. (2.5x100.0x4.18)
(1000x40.0)

C. (2.5x100.0x4.18x40.0)
1000

D. (2.5x1.0x4.18x40.0)
1000

3. Whatisthespecificheatcapacityofasubstance(incal/goC)if400caloriescause
25gofittogofrom60Cto190C?

Q=400cal,m=25g
Q=mc(TfTi)
c=0.12cal/gC

4. Whatwastheinitialtemperatureif250calorieswereappliedto100gofgoldand
thefinaltemperatureofthegoldwas175C?Thespecificheatcapacityofgoldis
0.031cal/gC.
Q=250cal,m=100g,c=0.031cal/gC,Tf=175C,Ti=?
Q=mc(TfTi)
250cal=(100g)(0.031cal/gC)(175CTi)
Ti=94C

KarenFounk,ShannonMendes

5. Themassm(ing)ofasubstanceofspecificheatcapacityc(inJg1K1)increasesbyt
(oC).WhatistheheatchangeinJ?

A. mct
B. mc(t+273)
C. mct
1000
D. mc(t+273)
1000

6. Whatisthefinaltemperatureif500caloriesareappliedto40gramsofcopperat
20C?Thespecificheatcapacityofcopperis0.092cal/gC.

Q=mc(TfTi)
Tf=156oC

7. Drawadiagramofanenergylevelpotentialdiagram
foranendothermicreaction.

8. Whatisthemolarheatcapacityofethylalcohol,C2H5OH,inunitsofJ/moloC,ifits
specificheatis0.586cal/goC?[Recall:Thereare4.18Joulespercalorie]

0.586calx 4.18J x46.08g

=112.9Jmol1oC1
goC
1cal mol

9.When8.0gofammoniumnitrate(NH4NO3)wasdissolvedin100mLofwaterthe
temperaturefellfrom19.0Cto14.5C.Calculatethemolarenthalpyofsolutionfor
ammoniumnitrate.
Q =cmT=4.18Jmol1oC1x(100g)x(14.519.0oC)=1881J
Hsystem =|qsurroundings|=(1881J)=endothermic
HNH3NO3=1881J

8.0gx(mol/80.04g)

=18819.405J=+19kJ

KarenFounk,ShannonMendes
10. Alaboratorytechnicianadds43.1mLofconcentrated,11.6mol/Lhydrochloricacid
towatertoform500.0mLofdilutesolution.Thetemperatureofthesolution
changesfrom19.2Cto21.8C.Calculatethemolarenthalpyofdilutionof
hydrochloricacidinkJ/mol.(4marks)

Q
=cmT

=4.18Jg1oC1x(500g)x(21.819.2oC) =5434J

Hsystem =|qsurroundings|

=(5434J)=exothermic

HHCl
=5434J

=10.9kJ/mol
1
1
(11.6mol L )(43.1mL)(1L/1000mL)

11. Considerthefollowingequationforthecombustionofhydrogen:

H2(g)+O2(g)H2O(g)+243kJ

Inordertoproduce1215kJofheat,howmanygramsofH2mustburn?

10.0g

12. Ifa2.34gsubstanceat22Cwithaspecificheatof3.88cal/gCisheatedwith124
calofenergy,whatisthenewtemperatureofthesubstance?

Q=cmT
124cal=3.88calg1oC1x(2.34g)x(Tf22oC)
Tf=35.7oC

13. Drawadiagramofanenergylevel
potentialdiagramforanexothermic
reaction.

KarenFounk,ShannonMendes
14. Whichtypesofreactionsarealwaysexothermic?
I. Neutralization
II. Decomposition
III. Combustion

A. IandIIonly
B. IandIIIonly
C. IIandIIIonly
D. I,IIandIII

15. Howmanygramsofaluminumcanbeheatedfrom90Cto120Cif500caloriesare
applied?Thespecificheatofaluminumis0.21cal/gC.

Q=500cal,m=?,c=0.21cal/gC,Tf=120C,Ti=90C

Q=mc(TfTi)
500cal=(m)(0.21cal/gC)(12090C)
m=79.4g

16. WhenthesolidsBa(OH)2andNH4SCNaremixed,asolutionisproducedandthe
temperaturedrops.

Ba(OH)2(s)+2NH4SCN(s)Ba(SCN)2(aq)+2NH3(g)+2H2O(l)

Whichstatementabouttheenergeticsofthisreactioniscorrect?

A. ThereactionisendothermicandHisnegative.
B. ThereactionisexothermicandHisnegative.
C. ThereactionisexothermicandHispositive.
D. ThereactionisendothermicandHispositive.

KarenFounk,ShannonMendes

Appendix B: Bingo Questions (Student copy)

1. Whatisthetemperaturechangeofa120gpieceofaluminumwhosespecificheatis
1.89J/gCafter1800Jofheatenergyisapplied?

2. 1.0gofsodiumhydroxide,NaOH,wasaddedto99.0gofwater.Thetemperatureof
thesolutionincreasedfrom18.0to20.5oC.Thespecificheatcapacityofthesolution
is4.18Jg1K1.WhichexpressiongivestheheatevolvedinkJmol1?

A. (2.5x100.0x4.18x1000)
40.0

B. (2.5x100.0x4.18)
(1000x40.0)

C. (2.5x100.0x4.18x40.0)
1000

D. (2.5x1.0x4.18x40.0)
1000

3. Whatisthespecificheatcapacityofasubstance(incal/goC)if400caloriescause
25gofittogofrom60Cto190C?

4. Whatwastheinitialtemperatureif250calorieswereappliedto100gofgoldand
thefinaltemperatureofthegoldwas175C?Thespecificheatcapacityofgoldis
0.031

5. Themassm(ing)ofasubstanceofspecificheatcapacityc(inJg1K1)increasesbyt
(oC).WhatistheheatchangeinJ?
A. mct
B. mc(t+273)
C. mct
1000
D. mc(t+273)

1000

KarenFounk,ShannonMendes
6. Whatisthefinaltemperatureif500caloriesareappliedto40gramsofcopperat
20C?Thespecificheatcapacityofcopperis0.092cal/gC.

7. Drawadiagramofanenergylevelpotentialdiagramforanendothermicreaction.

8. Whatisthemolarheatcapacityofethylalcohol,C2H5OH,inunitsofJ/moloC,ifits
specificheatis0.586cal/goC?[Recall:Thereare4.18Joulespercalorie]

9.When8.0gofammoniumnitrate(NH4NO3)wasdissolvedin100mLofwaterthe
temperaturefellfrom19.0Cto14.5C.Calculatethemolarenthalpyofsolutionfor
ammoniumnitrate.

10. Alaboratorytechnicianadds43.1mLofconcentrated,11.6mol/Lhydrochloricacid
towatertoform500.0mLofdilutesolution.Thetemperatureofthesolution
changesfrom19.2Cto21.8C.Calculatethemolarenthalpyofdilutionof
hydrochloricacidinkJ/mol.

11. Considerthefollowingequationforthecombustionofhydrogen:

H2(g)+O2(g)H2O(g)+243kJ

Inordertoproduce1215kJofheat,howmanygramsofH2mustburn?

12. Ifa2.34gsubstanceat22Cwithaspecificheatof3.88cal/gCisheatedwith124
calofenergy,whatisthenewtemperatureofthesubstance?

13. Drawadiagramofanenergylevelpotentialdiagramforanexothermicreaction.

KarenFounk,ShannonMendes
14. Whichtypesofreactionsarealwaysexothermic?
i. Neutralization
ii. Decomposition
iii. Combustion

1. IandIIonly
2. IandIIIonly
3. IIandIIIonly
4. I,IIandIII

15. Howmanygramsofaluminumcanbeheatedfrom90Cto120Cif500caloriesare
applied?Thespecificheatofaluminumis0.21cal/gC.

16. WhenthesolidsBa(OH)2andNH4SCNaremixed,asolutionisproducedandthe
temperaturedrops.

Ba(OH)2(s)+2NH4SCN(s)Ba(SCN)2(aq)+2NH3(g)+2H2O(l)

A. ThereactionisendothermicandHisnegative.
B. ThereactionisexothermicandHisnegative.
C. ThereactionisexothermicandHispositive.
D. ThereactionisendothermicandHispositive.

KarenFounk,ShannonMendes

Appendix C: Bingo Cards

BINGO INSTRUCTIONS:

1. NowthatyouhavefoundyourBINGOfamily,onememberfromyourteamwillclose
theireyesandrandomlypickaquestionfromthecup
2. Readoutthequestiontoyourfamilyandasateamsolvethequestion
3. Whenyouhavesolvedthequestion,lookfortheansweronyourBINGOsheetand
putthenumberofthequestionintheboxwiththeanswer
4. Theaimofthegameistogetfourboxesinarow,horizontally,verticallyor
diagonally.

BINGO CARD 1:

7.94C

35.7C

79.4g

156C

0.12cal/gC

94C

112.9J
mol1oC1

19kJ

10.0g

10.9kJ/mol

KarenFounk,ShannonMendes

BINGO INSTRUCTIONS:

1. NowthatyouhavefoundyourBINGOfamily,onememberfromyourteamwillclose
theireyesandrandomlypickaquestionfromthecup
2. Readoutthequestiontoyourfamilyandasateamsolvethequestion
3. Whenyouhavesolvedthequestion,lookfortheansweronyourBINGOsheetand
putthenumberofthequestionintheboxwiththeanswer
4. Theaimofthegameistogetfourboxesinarow,horizontally,verticallyor
diagonally.

BINGO CARD 2:

10.0g

112.9J
mol1oC1

19kJ

0.12cal/gC

7.94C

35.7C

94C

79.4g

156C

10.9kJ/mol

KarenFounk,ShannonMendes

BINGO INSTRUCTIONS:

1. NowthatyouhavefoundyourBINGOfamily,onememberfromyourteamwillclose
theireyesandrandomlypickaquestionfromthecup
2. Readoutthequestiontoyourfamilyandasateamsolvethequestion
3. Whenyouhavesolvedthequestion,lookfortheansweronyourBINGOsheetand
putthenumberofthequestionintheboxwiththeanswer
4. Theaimofthegameistogetfourboxesinarow,horizontally,verticallyor
diagonally.

BINGO CARD 3:

19kJ

112.9J
mol1oC1

10.0g

35.7C

7.94C

0.12cal/gC

94C

156C

79.4g

10.9kJ/mol

KarenFounk,ShannonMendes

BINGO INSTRUCTIONS:

1. NowthatyouhavefoundyourBINGOfamily,onememberfromyourteamwillclose
theireyesandrandomlypickaquestionfromthecup
2. Readoutthequestiontoyourfamilyandasateamsolvethequestion
3. Whenyouhavesolvedthequestion,lookfortheansweronyourBINGOsheetand
putthenumberofthequestionintheboxwiththeanswer
4. Theaimofthegameistogetfourboxesinarow,horizontally,verticallyor
diagonally.

BINGO CARD 4:

79.4g

156C

10.0g

35.7C

112.9J
mol1oC1

94C

0.12cal/gC

7.94C

19kJ

10.9kJ/mol

KarenFounk,ShannonMendes

BINGO INSTRUCTIONS:

1. NowthatyouhavefoundyourBINGOfamily,onememberfromyourteamwillclose
theireyesandrandomlypickaquestionfromthecup
2. Readoutthequestiontoyourfamilyandasateamsolvethequestion
3. Whenyouhavesolvedthequestion,lookfortheansweronyourBINGOsheetand
putthenumberofthequestionintheboxwiththeanswer
4. Theaimofthegameistogetfourboxesinarow,horizontally,verticallyor
diagonally.

BINGO CARD 5:

112.9J
mol1oC1

94C

156C

0.12cal/gC

10.0g

7.94C

19kJ

35.7C

10.9kJ/mol

79.4g

KarenFounk,ShannonMendes

BINGO INSTRUCTIONS:

1. NowthatyouhavefoundyourBINGOfamily,onememberfromyourteamwillclose
theireyesandrandomlypickaquestionfromthecup
2. Readoutthequestiontoyourfamilyandasateamsolvethequestion
3. Whenyouhavesolvedthequestion,lookfortheansweronyourBINGOsheetand
putthenumberofthequestionintheboxwiththeanswer
4. Theaimofthegameistogetfourboxesinarow,horizontally,verticallyor
diagonally.

BINGO CARD 6:

7.94C

35.7C

79.4g

156C

10.9kJ/mol

19kJ

0.12cal/gC

112.9J
mol1oC1

10.0g

94C

KarenFounk,ShannonMendes

BINGO INSTRUCTIONS:

1. NowthatyouhavefoundyourBINGOfamily,onememberfromyourteamwillclose
theireyesandrandomlypickaquestionfromthecup
2. Readoutthequestiontoyourfamilyandasateamsolvethequestion
3. Whenyouhavesolvedthequestion,lookfortheansweronyourBINGOsheetand
putthenumberofthequestionintheboxwiththeanswer
4. Theaimofthegameistogetfourboxesinarow,horizontally,verticallyor
diagonally.

BINGO CARD 7:

35.7C

94C

79.4g

156C

10.0g

19kJ

0.12cal/gC

7.94C

112.9J
mol1oC1

10.9kJ/mol