MATERIAL SAFETY DATA SHEET

TRADE NAME: Revision No.:04 563-ISOREACTIVE RED HE3B

According to 2001/58/EC

PAGE 1 OF 4

Revision Date: 09/01/2013

SECTION 1 PRODUCT AND COMPANY INFORMATION

TRADE NAME: TYPE OF USE: ISOREACTIVE RED HE3B
USED AS DYE FOR COLORATION OF TEXTILES

SECTION 2 COMPOSITION/INFORMATION ON INGRIDIENTS

CHEMICAL IDENTITY : C.I. NAME & NO: RED MIX CAS NO: 61951-82-4 EINECS NO: 263-351-0

SECTION 3 HAZARDOUS IDENTIFICATION

INFORMATION CONCERNING PARTICULAR HAZARDS FOR HUMAN AND ENVIRONMENT: NO HAZARDOUS TO HUMAN AND ENVIRONMENT ACCORDING TO GHS HAZARD CLASSIFICATION

SECTION 4 FIRST AID MEASURES

INHALATION: EYE CONTACT: SKIN CONTACT: INGESTION: REMOVE VICTIM TO FRESH AIR. GET IMMEDIATE MEDICAL HELP. RINSE THROUGHLY WITH WATER FOR 15 MINUTES. GET MEDICAL HELP IF IRRITATION CONTINUES. WASH WITH SOAP AND WATER. GET MEDICAL HELP IF IRRITATION CONTINUES. IF CONSCIOUS, GIVE WATER TO DILUTE STOMACH CONTENTS. GET MEDICAL HELP.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: SPECIAL PROTECTIVE EQUIPMENT: STANDARD PROCEDURE FOR CHEMICAL FIRES. WATER, DRY CHEMICAL, CO2, FOAM WEAR A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING

SECTION 6 ACCIDENTAL RELEASE MEASURE

PERSON-RELATED SAFETY PRECAUTIONS: WEAR PROTECTIVE EQUIPMENT. AVOID BREATHING VAPORS, MIST OR GAS.. MEASURES FOR ENVIRONMENTAL PROTECTION: PREVENT MATERIAL FROM ENTERING SEWERS, WATER WAYS. MEASURES FOR CLEANING/COLLECTING: SWEEP OR SHOVEL SPILLS IN TO APPROPRIATE CONTAINER FOR DISPOSAL.

SECTION 7 HANDLING AND STORAGE

HANDLING: KEEP RECEPTACLES TIGHTLY SEALED. AVOID INGESTION AND INHALATION USE WITH ADEQUATE VENTILATION PROTECT FROM HEAT INFORMATION FOR SAFE HANDLING: PERSON WHO SUFFERS FROM ASTHMATIC OR BREATHING PROBLEM SHOULD NOT HANDLE THIS DYE. INFORMATION ABOUT FIRE-AND EXPLOSION PROTECTION: THE PRODUCT IS NOT FLAMMABLE. STORAGE CONDITION: STORE IN SUITABLE LABELED CONTAINERS AND KEEP CONTAINERS CLOSED

MATERIAL SAFETY DATA SHEET

According to 2001/58/EC

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STORAGE FACILITIES: STORE IN A COOL AND DRY AREA WITH ADEQUATE VENTILATION STORE AWAY FROM OXIDIZING AND REDUCING AGENTS PROTECT FROM HEAT AND DIRECT SUNLIGHT.

TRADE NAME: Revision No.:04

563-ISOREACTIVE RED HE3B

Revision Date: 09/01/2013

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL FACILITIES: NO FURTHER DATA, SEE ITEM 7. PERSONAL PROTECTIVE EQUIPMENT: OTHER EQUIPMENT AND HYGIENIC MEASURES: WEAR APPROPRIATE EQUIPMENT TO HAZARD EXPOSURE. EYEWASH AND SAFETY SHOWER SHOULD BE PRESENT. WASH HANDS BEFORE EATING, DRINKING OR SMOKING. RESPIRATORY PROTECTION: APPROVED DUST OR MIST RESPIRATOR SHOULD BE USED IF AIRBORNE PARTICULATE IS GENERATED WHEN HANDLING THIS MATERIAL. PROTECTION OF HANDS: RECOMMENDED TO USE PROTECTIVE GLOVES. EYE PROTECTION: WEAR SPLASH-PROOF CHEMICAL GOGGLES. VENTILATION: LOCAL EXHAUST AND GENERAL ROOM VENTILATION ARE BOTH ESSENTIAL TO PREVENT ACCUMULATION OF FLAMMABLE VAPOUR OR DUST MIXTURE

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE AND ODOR: MELTING POINT: DECOMPOSITION TEMPERATURE: pH (1% IN WATER): SOLUBILITY IN WATER (G/L): DENSITY (KG / M3) VOC (EC): ORGANICS SOLVENTS: CHANGES IN PHYSICAL STATES MELTING POINTS/MELTING RANGE BOILING POINTS/BOILING RANGE FLASH POINT COMBUSTIBILITY EXPLOSION LIMITS IGNITION TEMPERATURE SELF-IGNITION TEMPERATURE SELF IGNITION EXPLOSION HAZARD FIRE PROMOTING PROPERTIES VAPOUR PRESSURE VISCOSITY RED POWDER, ODORLESS >200C >250C 6.5-7.5 100 (25C) 450-650 0.00% 0.00% NOT APLICABLE NOT APLICABLE NOT APLICABLE NOT APLICABLE NOT APLICABLE NOT APLICABLE NOT APLICABLE NOT APLICABLE NOT APLICABLE NOT APLICABLE NOT APLICABLE NOT APLICABLE

SECTION 10 STABILITY AND REACTIVITY

HAZARDOUS DECOMPOSITION ON EXPOSURE TO HIGH TEMPERATURE, MAY DECOMPOSE, RELEASING TOXIC VAPOURS. HAZARDOUS REACTIONS STABLE HAZARDOUS PROPERTIES NONE UNDER NORMAL CONDITIONS MATERIALS TO AVOID STRONG REDUCING AGENTS. OXIDIZING AGENT

SECTION 11 TOXICOLOGICAL INFORMATION

RAT ORAL LD50 [MG/KG] RABBIT DERMAL LD50 [MG/KG] RAT INHALATION LC50[MG/L/4H] > 2100 NO DATA AVAILABLE NO DATA AVAILABLE

MATERIAL SAFETY DATA SHEET

According to 2001/58/EC

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TRADE NAME: Revision No.:04

563-ISOREACTIVE RED HE3B

Revision Date: 09/01/2013

DERMAL IRRITATION (RABBIT) NOT AN IRRITANT EYES IRRITATION SLIGHT EYE IRRITANT ADDITIONAL TOXICOLOGICAL INFORMATION WHEN USED AND HANDLED ACCORDING TO SPECIFICATIONS, THE PRODUCT DOES NOT HAVE ANY HARMFUL EFFECTS TO OUR EXPERIENCE AND THE INFORMATION PROVIDED TO US.

SECTION 12 ECOLOGICAL INFORMATION

LC 50 (MG/L) WGK CLASS (GERMANY) BIODEGRADATION [%] ACUTE FISH TOXICITY AOX (% ORGANIC HALIDE) TOC VALUE VOC VALUE GENERAL NOTES: >1000 PPM (LEUCISCUS IDUS) WGK II 47-52% DOES NOT SHOW TOXICITY AT 101MG/L PERMANENT AOX NOT DETECTED 30% NON -VOC DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM

SECTION 13 DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: CONTAINER: DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. COMPLETELY EMPTY CONTENTS OF DRUMS BEFORE DISCARDING. DO NOT REUSE WITHOUT RECONDITIONING. DO NOT CUT OR WELD ON CONTAINER.

SECTION 14 TRANSPORT INFORMATION

LAND TRANSPORT (ADR/RID) NO CLASSIFICATION ASSIGNED INLAND TRANSPORT NO CLASSIFICATION ASSIGNED SEA TRANSPORT (IMDG) NO CLASSIFICATION ASSIGNED AIR TRANSPORT NO CLASSIFICATION ASSIGNED GENERAL INFORMATION NOT CLASSIFIED AS HAZARDOUS UNDER TRANSPORT REGULATION.

SECTION 15 REGULATORY INFORMATION

LABELLING ACCORDING TO EU GUIDELINES: THE PRODUCT IS NOT SUBJECT TO IDENTIFICATION REGULATIONS UNDER EU DIRECTIVES AND THE ORDINANCE ON HAZARDOUS MATERIALS (GERMAN GEFSTOFF V). OTHER REGULATORY CONTROLS: COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY. THIS PRODUCT HAS BEEN REVIEWED FOR SARA TITLE III.

SECTION 16 OTHER INFORMATION

REASON FOR REVISION: REVISED THE SDS ACCORDING TO GHS HAZARD COMMUNICATION. SOURCES EUWAS - EUROPEAN WASTE SECTOR ASSISTANT HTTP://WWW.EUWAS.ORG/CONTENT DATA FROM ETAD GUIDANCE ON HAZARD LABELING OF REACTIVE DYES HTTP://WWW.ISS.IT/BINARY/BDSE/CONT/ETAD%202000.1171641998.PDF DISCLAIMER: INFORMATION CONTAINED HERE IN IS BASED ON THE PRESENT STATE OF OUR KNOIWLEDGE. WE BELIEVE THAT ALL THE DATA AND INFORMATION GIVEN IS ACCURATE AS OF DATE OF PREPARATION AND IS OFFERED IN GOOD FAITH BUT WITHOUT WARRANTY OF REPRESENTATION. SINCE CONDITIONS OF USE ARE BEYOND OUR CONTROL, WE DISCLAIM ALL LIABILITY FOR RELIANCE THEREON. THIS IS OFFERED SOLELY FOR CONSIDERATION, INVESTIGATION AND VERIFICATION.