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1 when ether is exposed to air for sometimes an explosive substance is produced is (a) Peroxide (b) TNT (c) oxide

(d) superoxide 2. The product of heating C2H5Br in presence of DRY silver oxide is (a) C2H5OC2H5 (B) C2H5COOH(C) C2H5OH (D) C2H5CHO 3. WHICH OF THE FOLLOWING WILL REDUCE DIETHYL ETHER INTO ETHANE AND ETHANOL (A) Na/liq NH3 (b)cold HI (c) H2SO4/high pressure (d) Al2O3 /heat 4. Ph-OH +C2H5I (C2H5O/ANHY C2H5OH )-A (A) Ph-OC2H5 (B) C2H5-O-C2H5 (C) C6H5-I 5. O-DIHYDROXY-PHENOL +CH2I2/NaOH -- 0 0

(a) wurtz reaction (b) wittig reaction (c) Ulman reaction (d) William reaction 6. Anisole(Ch3)3CCl/Alcl3(anhy)Cl2/Fecl3HBr/Heat X Find the product 7. Anisole ---HBr- Product find the product 8. A tertiary alcohol H upon treatment of acid catalysed dehydration gives product I , ozonlysis of I leads to compounds J and K . Compound J on reaction with KOH gives benzyl alcohol and a compound L where as on treatment with KOH gives benzyl alcohol and M Identify all of them (IIT 2009) 9. Which of the following has S configuration

10. The number of optical isomer of CH3CH(OH)CH(OH)CHO (a) Zero(b) 2 (c)3 (d)4 11. which of the following is not chiral (a) 2,3-dibromopropane (b) 3-bromo pentane (c) 2-hydroxypropanoic acid (d) 2butanol 12.which of following is meso isomer ?

(a) 2-chlorobutane (b) 2,3-dichlorobutane (c) 2,3-dichrlopeantan (d) 2hydroxypropanoic acid

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