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EUROPEAN STANDARD EN 589 NORME EUROPEENNE EUROPAISCHE NORM ‘August 2008 (8 75.160.20 ‘Supersedos EN 589:2004 English Version Automotive fuels - LPG - Requirements and test methods Carburars pour automobiles - GPL.» Exigonces ot ‘rato or Krattahreuge-Flssiggas- Anforderungen ‘métoges deasal ‘nd Pratvertanen ‘Ne Eurcpean Standard was approved by CEN on 29 June 2008, Under e aopeee’ ee in eaves (Enlsh. Frnch German. veson any ‘ther language mace by transition Chil vowing HY 12 CEN member ios own langue and oe ow CEN Marae eae ‘same status as the oficial versione France, Gomary roca ganda bcs o Auta, ebun, Bugafa. Cy, Czech Repub, Danmark, Ears Fare, Famer Seen ee, HUNGRY. cand rand, hay at, Thun, CsceonuG ake eee Norway. Poland, Portugal, Fomana, Stake, Soveria, Spain, Sweden, Swizerare/ and Unted Kensoes EUROPEAN COMMITTEE FOR STANDARDIZATION COMITE EUROPEEN DE NORMALISATION EUROPAISCHES KOMITEE FUR NORMUNG Management Cente: ue de Stassart, 26. B-1050 Brussole (©2008 CEN Al oghs of explotation n any form and by any means reserved ol, No. EN 589-2008: & worldwide fr CEN national Members ‘remewanen a: TYKOHLT HE®TOXHM BYPFAC AM Mopvura 600 / 24.06.2009, rans or BKC EN 589:2008 (E) Normative references. ‘Terms and definitions. ‘Sampling. Annex A (normative) Test method for odour of LPG Aa’ Introduction . 54 Calculation and expression of tosis BS Reporting Annex C (normative) Absolute vapour pressure blending factors (kPa) Annex D (informative) Seasonal gauge vapour pressure lim) Bibliography.. ossvaonasen a: TVKOML HE@TORUM BYPTAC AN Tlopwa 680 / 24.06.2009, wommvena or BAC EN 689:2008 (E) Foreword prenusgoument (EN §89:2008) has been prepared by Technical Commitee CEN/TC 19 “Petroleum Products, lubricants and related products’, the secretariat of whichis held by NEN. a nieufGpean Standard shall be given the status of a national standard, ether by publication of an se ay xt or by endorsement, at the latest by February 2009, and conflicting national searchns ren bbe withdrawn at the latest by February 2008, Patent ares ai fo the Possibility that some ofthe elements of his document may be the subject of Fang, "OS CEN [and/or CENELEC] shall not be held responsible for kdentying any oll such patooe Fights. This document supersedes EN 589:2004 ; “ Differences between this document and EN 589:2004 include: —_Inttoducton of two new test methods for residues replacing the formerly applied ENN 18013757 [1], — introduction of @ revised specification of residue content, — introduction of a new test method for free water detection, update ofthe values in Table C.1 in terms of the numberof digits, nex. the Technical Corrigendum on the 2004 edltion on Table B.1, 3s published in 2005, has been incorporated ‘Pecotcing to the CENICENELEC Internal Regulations, the national standards organizations of the Gyonting countries ere Bound to implement this European Standard: Austria, Belgium, Bulger, ripnis, Czech Repubic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, loser, and, tly, Levis, Lithuania, Luxembourg, Malta, Netheriands, Norway, Poland, Portugal, Rowen, Stovakia, Slovenia, Spain, Siveden, Switzerland end the United Kingdom ‘Aipeanasneven ae: JTYKOFLT HE@TOXHM BYPTAC All Foperxa 6800 / 24.06.2009, xamsnnewa or BHC EN 589:2008 (E) 1 Scope Tn {izopean Standard species requtements and test methods for marketed and delivered automative 26 (Lauefied Petroieum Gas). is appicable to automotive LPG for use in LPG engine vehles designed torun on automotive LPG, NOTE: For the purpotes of hi European Standard, the tm "i (V/V is used to represent the volume fection Te re nettention is drawn to the risk of fire and explosion when handling LPG and to the hazard to health which arises through inhalation of excessive amounts of LPG. Fe lease ant volatile hydrocarbon liquid which is normaly stored under pressure. the pressure is released large volumes of gas willbe produced which form flammable mixtures with or nceae Franling abe teamately 2%4(WA to 40% (VM. This European Standard involves tho sampling, Lagiling and testing of LPG. All procedures should be conducted away from sources cesiy pertonned se ames: unprotected electrical equipment and electrostatic hazards. Testing cheno oe erformed as far as practicable under an slectrically-safe ventilation hood. Should uid form ean cause cold burns to the skin, Protective clathing such as gloves and goggles ‘Should be worn if contact with the skin is likely to occur. Unnecessary inhalation of LPG vapour should be avoided. The operator should not be exposed to atmospheres containing more than 1 800 mgim' over an 8 h timesweighted average (TWA) reference Reriod. or more than 2.250 mgim’ over a short term, 10min reference period. Ove oy the tests estribed in this European Standard involves the operator inhaling a mixture of air ond Loc, vapour. Farticulat. attention is drawn to the cautionary statement provided in At, where wis method is referred to, 2 Normative references Tre Colowing referenced documents are indispensable for the application of this document. For dated Suerences only the edition cited applies. For undated references. the latest edion of the erences document (including any amendments) appiies. ropes’ 2007, Petroleum products ~ Test method for tree water in liquefied petroleum gas by visual inspection Soar Z0c7. Liqueried petroleum gasés = Determination of dissolved residues - High temperature Gee ‘chromatographic method Feaeg? 12007. Liquefied petrtoum gases ~ Determination of dissolved residues - High temperature gravimetric method 1901285 ei AO88. Liguetied petroleum gases - Determination of gauge vapour pressure - LPG method (1S0 4256: 1996) EN ISO 4267:2001, Liquefied petrooum gases - Method of sampling (1S0 4267:2001) Fr ge f758:2006, Petroleum products - Determination and application of precision data in relation to ‘methods of test (ISO 4259:2006) 190 orien 99°: “iauetied petroleum gases - Comosiveness to copper - Copper stip test (ISO 6251;1996) Fn Se 8818-1995, Liqueried petroleum gases - Detection of hydrogen sulfide - Lead scetate method (ISO 8819-1993) FSO S07 sa1288. Liauetied petroleum gases - Calculation method for density and vapour pressure (ISO 69731997) 4 "psansanaven au: YKOHAN HEGTOXHM BYPTAC A/\ Topwera 6800/ 24.06.2008, inrumiena or BHC EN 589:2008 (E) Fomenceo:1994, Petroleum products and hydrocarbons - Determinetion of sulfur content ~ Wiekbold combustion method (ISO 4260:1987) £N27941:1983, Commercial propane and butane - Analysis by gas chromatography (ISO 7941: 1988) ASTM D 3246-06, Standard fest method for sullurn petroleum gas by oxidative ‘microcoulometry A leh Ot. Standard test method for determination of total volatile sultur in gaseous ‘hydrocarbons 4nd liquefied petroleum gases by ultraviolet fluorescence 3. Terms and definitions For the purposes ofthis document, the following terms and definitions apply. 34 liquefied petroleum gas (LPG) eet at mGas that can be stored andor handled inthe liquid phase under moderate conditions of pressure Propane rent temperature. consisting predominantly of propane, bulanes, with small Bosoone cr ropene, butenes and pentanes/pentenes 4 Sampling Samples shall be taken as described in EN ISO 4257 and/or in accordance with the requirements of national Standards oF regulations for the sampling of automotive LPG. The national requirements shall be eet eat detail or shall be referred to by reference in a national annex to this European Standard Hae.cf te sensitivity of some ofthe fest methods referred to in this European Standard, particular attention Shall be pic to compliance with any guidance on sampling containers which ie included Ih the tod meting standard, NOTE 1 Ris important thatthe sampling procedure is followed in detail in order to avoid evaporation losses. Tn 3 peat, Sampling from the dispenser hose, 201 of product should be pumped or recirculated, in order oblain a representatve sample, 5 Pump marking Information to be marked on dispensing pumps used for delivering automotive LPG, and the dimensions of ‘Re mark shall be in accordance with the requirements of national standards or regulations forthe marking of Pumps for automotive LPG. Such requirements shall be set out in detail or shall be referred to by reference in a national annex to this European Standard, 6 Requirements and test methods 61 General Wich ested by the methods of test given in Table 1, automotive LPG fuel shall comply with the Imiting requlrements specified in that Table. For the minimum vapour pressure, five grades, A. B, C, D and E are given to allow for seasonal limits to be Set nationally for each period of the year. In a national annex to this European Standard, each countty shall indicate which grade(s) it adopts to achieve a minimum vapour pressure of 150 kPa (gauge) throughout the ‘entire year and shall detail the date range in which the selected grade applies. ‘peasnaven se: TYKOPLT HE@TOXHM BYPTAC All Tlopwixa 6800 /24.06:2009,wamauena or BHC EN 589:2008 (E) Table 4 - Requirements and test methods 62 Water content aed petroleum gases for automotive purposes shall not contaln fee water at 0°C and at the saturated ‘Vapour pressure on visual inspection. Setees mi CaRrePane rch mixtures wth a minimum of 80 % propane, compliance with ENISO 13768 [1] equally Stites this requirement, bo acne ona! Purposes i is allowed to add up to 2 000 mgkg methanol. No other antireeze agents shall be added, When tested in accordance with the procedure described in Annex A, the odour of the 928 shal be Rammctite ac: $stetve and unpleasant), detectable at a concentration ins of 20 Sb Mer lower flammability limit. Rreanaswavew 2: TVKOHL HEOTOXHM BYFTAC All lope 6800/2406.2009, samen or BHC Property Unit Limits Test method * ; (See 2, Nomatve Minimum Maximum | (Sez Noma Motor octane number, MON 29,0 Annex 8 Total dienes content 5 {including 1.3 butadiene) eae oe [eNarei #3 Hydrogen sulphide negative ENISO 8819 - < ENZA060 (emer setcoment mong 50 | ASTM 3246 9) ‘ASTM.D 6667 Copper stip corrosion : | Creaoey rating cass 4 EN 180 6251 ENTea7o Evaporation residue mang so fey ew . Vapour pressure, gauge, ENISO 4265 —S>C YS atan°ce one kPa 1850 | EN1S0.8973 and @ é Annex ¢ : Vapour pressure, gauge, min, ~ = Letete , 150KPa atatemperature of #* | *C Eee fe for grade A = for grade B =forgrade “for grade D +10 =for grade E +20 Wiater content" Pass EN 15469 ~ Unpleasant and dstnaiive at | Soe 6 and Scour 20%LFL Annex A See ass TST 7 7 ® Bee also 652. See aso 6.5.3. force Puroge ofthis standard EN ISO 8073 together wh Annex anal be apped st te indicated Seco caay £2 Mal own qutty conta purposes, tw valves 2 nen henkemsnc ea ee aso be used # See aso 6 ! 06 38962 EN 689:2008 (E) NOTE _Unpleasent boing subjective, the odour shouldbe a caution and inviting tothe user to search forthe leak. 64 Density a density report is required, EN ISO 3983 [3] or EN ISO 8973 are recommended, 65 Precision and dispute 8.5.1 Al test methods referred to in this European Standard include a precision statement, in cases of

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